Long-chain cyclic carbonates (LC-CC) are attractive building blocks and non-ionic surfactants. We demonstrate a convenient methodology to prepare LC-CC in miniemulsions of epoxide droplets in water. The pre-organization and confinement of the reagents from H-bond and hydrophobic interactions allow the target process to proceed at mild temperatures under atmospheric CO2.
Hydrophobically-enhanced “on water” cycloaddition of CO2to long-chain terminal epoxides
D'Elia V.
Co-ultimo
;
2022-01-01
Abstract
Long-chain cyclic carbonates (LC-CC) are attractive building blocks and non-ionic surfactants. We demonstrate a convenient methodology to prepare LC-CC in miniemulsions of epoxide droplets in water. The pre-organization and confinement of the reagents from H-bond and hydrophobic interactions allow the target process to proceed at mild temperatures under atmospheric CO2.File in questo prodotto:
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