Hexavalent chromium was stabilized in soil by using a mixture of glass and aluminum recovered from municipal solid wastes under alkaline hydrothermal conditions. Cr(VI) concentration was reduced by 94–98% already after 7 days of treatment. After the same period, more than 90% of total Cr was stabilized in highly recalcitrant and scarcely mobile chemical forms, with 50% in the residual fraction (when the samples were treated at 1/10 w/w mixture/soil ratio). Longer treatments increased Cr stabilization. X-ray microanalyses revealed that Cr was stabilized in geopolymeric structures within large aluminosilicate mineral aggregates (containing both amorphous and crystalline phases). 3D microstructural analyses showed a limited compaction of the soil with still a 20% internal porosity in the neoformed aggregates. Increased pH and salinity after the treatment can be restored by simple soil amendments and washing.

Alkaline hydrothermal stabilization of Cr(VI) in soil using glass and aluminum from recycled municipal solid wastes

Gattullo C. E.;Allegretta I.;Spagnuolo M.;
2018-01-01

Abstract

Hexavalent chromium was stabilized in soil by using a mixture of glass and aluminum recovered from municipal solid wastes under alkaline hydrothermal conditions. Cr(VI) concentration was reduced by 94–98% already after 7 days of treatment. After the same period, more than 90% of total Cr was stabilized in highly recalcitrant and scarcely mobile chemical forms, with 50% in the residual fraction (when the samples were treated at 1/10 w/w mixture/soil ratio). Longer treatments increased Cr stabilization. X-ray microanalyses revealed that Cr was stabilized in geopolymeric structures within large aluminosilicate mineral aggregates (containing both amorphous and crystalline phases). 3D microstructural analyses showed a limited compaction of the soil with still a 20% internal porosity in the neoformed aggregates. Increased pH and salinity after the treatment can be restored by simple soil amendments and washing.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11587/476500
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