Impact of metalloporphyrin-based porous coordination polymers on catalytic activities for the oxidation of alkylbenzene

X. -F., Lu; Y. X., Du; Mele, G.; Li, J.; W. -K., Ni; Zhao, Y. -G.

doi:10.1002/aoc.5501

Seven metalloporphyrin-based porous coordination polymers: Feш (TZP)Poly (CP1), CoII (TZP)Poly (CP2), NiII (TZP)Poly (CP3), CuII (TZP)Poly (CP4), ZnII (TZP)Poly (CP5), MnII (TZP)Poly (CP6), PbII (TZP)Poly (CP7) (TZP = 5,10,15,20- tetrakis[4-(2,3,4,5-tetrazolylphenyl)] porphyrin) were prepared and characterized. CP1−CP7 are amorphous aggregation supported with lower crystallinity by scanning electron microscopy, Brunauer−Emmett−Teller and powder X-ray diffraction. These coordination polymers exhibit effective dye scavenging and catalytic activities toward the oxidation of alkylbenzene to ketones and can be reused by filtration with a slight decreasing of catalytic activities. Metal atoms metalloporphyrin polymers have a great influence on the catalytic activities of metalloporphyrin polymers.

Titolo:	Impact of metalloporphyrin-based porous coordination polymers on catalytic activities for the oxidation of alkylbenzene
Autori:	Lu X. -F. [Writing – Original Draft Preparation] Du Y. X. [Data Curation] MELE, Giuseppe Agostino [Writing – Review & Editing] Li J. [Supervision] (Corresponding) Ni W. -K. [Membro del Collaboration Group] Zhao Y. -G. [Membro del Collaboration Group] mostra contributor esterni nascondi contributor esterni
Data di pubblicazione:	2020
Rivista:	APPLIED ORGANOMETALLIC CHEMISTRY
Abstract:	Seven metalloporphyrin-based porous coordination polymers: Feш (TZP)Poly (CP1), CoII (TZP)Poly (CP2), NiII (TZP)Poly (CP3), CuII (TZP)Poly (CP4), ZnII (TZP)Poly (CP5), MnII (TZP)Poly (CP6), PbII (TZP)Poly (CP7) (TZP = 5,10,15,20- tetrakis[4-(2,3,4,5-tetrazolylphenyl)] porphyrin) were prepared and characterized. CP1−CP7 are amorphous aggregation supported with lower crystallinity by scanning electron microscopy, Brunauer−Emmett−Teller and powder X-ray diffraction. These coordination polymers exhibit effective dye scavenging and catalytic activities toward the oxidation of alkylbenzene to ketones and can be reused by filtration with a slight decreasing of catalytic activities. Metal atoms metalloporphyrin polymers have a great influence on the catalytic activities of metalloporphyrin polymers.
Handle:	http://hdl.handle.net/11587/441067
Appare nelle tipologie:	Articolo pubblicato su Rivista

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