This article reports a simple and efficient synthesis of methyl(trifluoromethyl)oxaziridines, a new family of organic oxidizing agents. A detailed study on their oxygen transfer capability with respect to styrene, thioanisole and benzyl alcohol as model substrates for the synthesis of epoxides, sulfoxides and aldehydes is described. Moreover, an oxaziridine auto-oxidation at nitrogen and/or N-benzylic carbon is also reported.
Synthesis and reactivity of trifluoromethyl substituted oxaziridines
PERRONE, SERENA;ROSATO, FRANCESCA;Salomone, Antonio;TROISI, Luigino
2013-01-01
Abstract
This article reports a simple and efficient synthesis of methyl(trifluoromethyl)oxaziridines, a new family of organic oxidizing agents. A detailed study on their oxygen transfer capability with respect to styrene, thioanisole and benzyl alcohol as model substrates for the synthesis of epoxides, sulfoxides and aldehydes is described. Moreover, an oxaziridine auto-oxidation at nitrogen and/or N-benzylic carbon is also reported.File in questo prodotto:
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