In this work it is described a new synthetic pathway for the synthesis of bis-cresolate Pt(II) complexes with (N-N) dinitrogen ligands. In particular, we were able, for the first time, to isolate, in the solid state, both anti-[Pt(N-N)(4-Me-C6H4O)2], N-N = 1,10-phenanthroline, (Head to Tail, HT) and syn-[Pt(N-N)(4-Me-C6H4O)2], N-N = 2,2’-bipyridile, (Head to Head, HH) rotamers, which were also characterized by single crystal X-ray diffraction
New insights on the reactivity of [Pt(h2-C2H4)Cl(N-N)]+, N-N = diimine ligand, with phenolate derivatives. Single crystal X-ray structures of syn- and anti-[Pt(N-N)(4-Me-C6H4O)2] rotamers
BENEDETTI, MICHELE;ANTONUCCI, DANIELA;Chiara R. Girelli;FANIZZI, Francesco Paolo
2013-01-01
Abstract
In this work it is described a new synthetic pathway for the synthesis of bis-cresolate Pt(II) complexes with (N-N) dinitrogen ligands. In particular, we were able, for the first time, to isolate, in the solid state, both anti-[Pt(N-N)(4-Me-C6H4O)2], N-N = 1,10-phenanthroline, (Head to Tail, HT) and syn-[Pt(N-N)(4-Me-C6H4O)2], N-N = 2,2’-bipyridile, (Head to Head, HH) rotamers, which were also characterized by single crystal X-ray diffractionFile in questo prodotto:
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