Abstract Reaction of octakis(ethylthio) porphyrazine (H(2)OESPz) with FeBr2 in ClCH2CH2OH at 135 degrees C affords the 2-chloroethoxy-iron(III)-(ethylthio)porphyrazine, (ClCH2CH2O)Fe(III)OESPz, (LFe(III)OESPz) in good yield. The spectroscopic, redox, and coordination properties of the complex and its mu-oxo dimer derivative, [Fe(III)OESPz](2)O, are investigated and compared to those of the iron(III) porphyrin analogs.
Synthesis, coordination chemistry, and physico-chemical properties of the 2-chloroethoxy-iron(III)(ethylthio) porphyrazine
GUASCITO, Maria Rachele;
2013-01-01
Abstract
Abstract Reaction of octakis(ethylthio) porphyrazine (H(2)OESPz) with FeBr2 in ClCH2CH2OH at 135 degrees C affords the 2-chloroethoxy-iron(III)-(ethylthio)porphyrazine, (ClCH2CH2O)Fe(III)OESPz, (LFe(III)OESPz) in good yield. The spectroscopic, redox, and coordination properties of the complex and its mu-oxo dimer derivative, [Fe(III)OESPz](2)O, are investigated and compared to those of the iron(III) porphyrin analogs.File in questo prodotto:
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