Exposure of solid trans-[Pt(PHCy2)(2)(PCy2)Cl] (1) to dry oxygen unexpectedly leads to [PtCl(PHCy2){(PCy2O)(2)H}] (2) as the major product, the formation of which has been followed by NOESY H-1 NMR techniques.
PtCl(PHCy2)(PCy2O)(2)H: a hydrogen bonded phosphinito complex obtained by direct reaction of molecular oxygen with a terminal phosphido complex
FANIZZI, Francesco Paolo;CICCARELLA, Giuseppe
2004-01-01
Abstract
Exposure of solid trans-[Pt(PHCy2)(2)(PCy2)Cl] (1) to dry oxygen unexpectedly leads to [PtCl(PHCy2){(PCy2O)(2)H}] (2) as the major product, the formation of which has been followed by NOESY H-1 NMR techniques.File in questo prodotto:
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