A mild and efficient one-pot synthesis of esters based on the Pd-catalyzed alkoxy- and aryloxycarbonylation of allylic and benzylic halides is described. The methodology has been applied to primary, secondary, and tertiary alcohols as well as to phenol derivatives. The O-protection of some biologically relevant molecules is also reported.

One-Pot Ester Synthesis from Allyl an Benzyl Halides and Alcohols by Palladium-Catalyzed Carbonylation.

S. PERRONE;Salomone, Antonio;TROISI, Luigino
2012-01-01

Abstract

A mild and efficient one-pot synthesis of esters based on the Pd-catalyzed alkoxy- and aryloxycarbonylation of allylic and benzylic halides is described. The methodology has been applied to primary, secondary, and tertiary alcohols as well as to phenol derivatives. The O-protection of some biologically relevant molecules is also reported.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11587/369131
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