Paramagnetic Fe(I) and Fe(III) complexes FeHL2 (I) and [FeHClL2]X (II) [L = (Ph2PCH2)2; X = BF4, ClO4] were prepd. from FeHClL2 by Na redn. and Ph3CBF4 or AgClO4 oxidn., resp. I and II were characterized by ir and magnetic susceptibility data and reactions of I with ClO4-, iodine, HCl, and (Ph3C)(ClO4) were studied.
Paramagnetic hydrido complexes of iron(I) and iron(III)
VASAPOLLO, Giuseppe;
1975-01-01
Abstract
Paramagnetic Fe(I) and Fe(III) complexes FeHL2 (I) and [FeHClL2]X (II) [L = (Ph2PCH2)2; X = BF4, ClO4] were prepd. from FeHClL2 by Na redn. and Ph3CBF4 or AgClO4 oxidn., resp. I and II were characterized by ir and magnetic susceptibility data and reactions of I with ClO4-, iodine, HCl, and (Ph3C)(ClO4) were studied.File in questo prodotto:
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