LNi(CONHR)Cl [I, L = 2,6-bis(diphenylphosphinomethyl)pyridine; R = Bu, PhCH2, R1C6H4, R1 = H, o-, p-Me, p-MeO, -Cl, -NO2) were prepd. by treating LNiCl2 with RNH2 and CO. LNi(CO2Me)Cl was prepd. by treating LNiCl2 in MeOH with CO and NaOMe. I react with bases to give isocyanates, urethanes or ureas.
Carbamoyl and alkoxycarbonyl complexes of nickel(II)
VASAPOLLO, Giuseppe
1984-01-01
Abstract
LNi(CONHR)Cl [I, L = 2,6-bis(diphenylphosphinomethyl)pyridine; R = Bu, PhCH2, R1C6H4, R1 = H, o-, p-Me, p-MeO, -Cl, -NO2) were prepd. by treating LNiCl2 with RNH2 and CO. LNi(CO2Me)Cl was prepd. by treating LNiCl2 in MeOH with CO and NaOMe. I react with bases to give isocyanates, urethanes or ureas.File in questo prodotto:
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