[MoCl(CO)3(η5-C5H5)] on photolysis with allyl or crotyl halides C5H4RX gives Mo(IV) complexes [MoX2(CO)(η3-C3H4R)(η5-C5H5)] (R = H, X = Cl, Br, I; R = Me, X = Cl, Br). [WCl(CO)3(η5C5H5)] under similar conditions gives trihalides [WX3(CO)2(η5-C5H5)] [X = Cl, Br) on reaction with C3H5Cl and C3H5Br while [WCl(CO3)(η5-C5H4SiMe3)] and [CrI(CO)3(η5-C5H5)] react with allyl chloride to give [WCl3(CO)2(η5-C5H4SiMe3)] and [CrCl2(η5-C5H5)], resp.
Photochemical reactions of allyl and crotyl halides with cyclopentadienylchromium, - molybdenum and -tungsten complexes
VASAPOLLO, Giuseppe
1985-01-01
Abstract
[MoCl(CO)3(η5-C5H5)] on photolysis with allyl or crotyl halides C5H4RX gives Mo(IV) complexes [MoX2(CO)(η3-C3H4R)(η5-C5H5)] (R = H, X = Cl, Br, I; R = Me, X = Cl, Br). [WCl(CO)3(η5C5H5)] under similar conditions gives trihalides [WX3(CO)2(η5-C5H5)] [X = Cl, Br) on reaction with C3H5Cl and C3H5Br while [WCl(CO3)(η5-C5H4SiMe3)] and [CrI(CO)3(η5-C5H5)] react with allyl chloride to give [WCl3(CO)2(η5-C5H4SiMe3)] and [CrCl2(η5-C5H5)], resp.File in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
