Primary aliph. and arom. amines react with carbon monoxide and di-tert-Bu peroxide in alc., catalyzed by PdCl2 and CuCl2 to give carbamates in good yields; double carbonylation to oxamates, using the peroxide or O, resulted from the use of secondary amines.
Conversion of primary amines to carbamate esters using palladium chloride and di-tert-butyl peroxide. Double carbonylation of secondary amines
VASAPOLLO, Giuseppe;
1987-01-01
Abstract
Primary aliph. and arom. amines react with carbon monoxide and di-tert-Bu peroxide in alc., catalyzed by PdCl2 and CuCl2 to give carbamates in good yields; double carbonylation to oxamates, using the peroxide or O, resulted from the use of secondary amines.File in questo prodotto:
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