Some previously synthesized nitrosoarene complexes of known coordination mode have been studied by XPS spectroscopy. New nitrosoarene complexes of RhIII, IrIII, CuI and HgII, e.g. Cl3Rh(PhNO)2, have been synthesized and studied by both x-ray photoelectron and IR spectroscopy. A correlation was found between the value ΔEB(O-N) and the bonding mode of the nitroso ligand.
Nitrosoarene complexes of rhodium(III), iridium(III), copper(I) and mercury(II). Use of XPS in determining the mode of bonding to transition metals
VASAPOLLO, Giuseppe;
1989-01-01
Abstract
Some previously synthesized nitrosoarene complexes of known coordination mode have been studied by XPS spectroscopy. New nitrosoarene complexes of RhIII, IrIII, CuI and HgII, e.g. Cl3Rh(PhNO)2, have been synthesized and studied by both x-ray photoelectron and IR spectroscopy. A correlation was found between the value ΔEB(O-N) and the bonding mode of the nitroso ligand.File in questo prodotto:
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