Two nitrosodithiofulvenes and a nitrosodiselenafulvene formed insol. coordination compds. with Pd chloride, these being the 1st reported coordination compds. of nitrosoalkenes. PdCl2.RNO and PdCl2.(RNO)2 were formed. Variable temp. NMR studies of the nitrosoalkenes demonstrate that the free energy barrier to rotation about the bond is low, values being in the range 58-93 kJ mol-1.
Nitrosoalkenes and their coordination compounds with palladium chloride
VASAPOLLO, Giuseppe;
1994-01-01
Abstract
Two nitrosodithiofulvenes and a nitrosodiselenafulvene formed insol. coordination compds. with Pd chloride, these being the 1st reported coordination compds. of nitrosoalkenes. PdCl2.RNO and PdCl2.(RNO)2 were formed. Variable temp. NMR studies of the nitrosoalkenes demonstrate that the free energy barrier to rotation about the bond is low, values being in the range 58-93 kJ mol-1.File in questo prodotto:
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