The synthesis of alcohols from aromatic olefins is described using a rhodium catalyzed hydroformylation reduction sequence with the assistance of a tertiary diamine ligand. The alcohols are produced in excellent branched to linear ratio and in good to excellent isolated yields. In all cases no aldehyde product, from hydroformylation, or alkyl product, from olefin reduction, was detected
Synthesis of Alcohols via a Rhodium Catalyzed Hydroformylation Reduction Sequence using Tertiary Bidentate Amine Ligands
VASAPOLLO, Giuseppe;
2013-01-01
Abstract
The synthesis of alcohols from aromatic olefins is described using a rhodium catalyzed hydroformylation reduction sequence with the assistance of a tertiary diamine ligand. The alcohols are produced in excellent branched to linear ratio and in good to excellent isolated yields. In all cases no aldehyde product, from hydroformylation, or alkyl product, from olefin reduction, was detectedFile in questo prodotto:
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