Amides can be prepared from allyl or benzyl halides and primary or secondary amines, using Pd(0) catalyst under CO pressure, in a one-pot synthesis. The reaction proceeds through the acyl palladium halide formation which undergoes an acylic nucleophilic substitution from the amine.
One-pot amide synthesis from allyl or benzyl halides and amines by Pd-catalysed carbonylation
TROISI, Luigino;GRANITO, Catia;ROSATO, FRANCESCA;
2010-01-01
Abstract
Amides can be prepared from allyl or benzyl halides and primary or secondary amines, using Pd(0) catalyst under CO pressure, in a one-pot synthesis. The reaction proceeds through the acyl palladium halide formation which undergoes an acylic nucleophilic substitution from the amine.File in questo prodotto:
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