Improvement and Metrological Validation of TDR-Methods for the Estimation of Static Electrical Conductivity

Accurate measurement of the static electrical conductivity provides a great insight into the characteristics and quality status of various materials. To overcome some limitations of the traditional measurement methods, there has been a growing interest toward the investigation of enhanced techniques for measuring electrical conductivity. In this regard, time-domain reflectometry (TDR) has attracted considerable attention, also due to the possibility of simultaneously monitoring different physical parameters. Although initially introduced for monitoring soil properties, the application of the TDR-based technique might be an interesting and cost-effective means in many other fields. However, the accuracy of traditional TDR-based electrical conductivity measurements is strongly influenced by the preliminary calibration technique. On such basis, in this paper, two innovative approaches for a more straightforward and accurate evaluation of the electrical conductivity are presented. The first method relies on the combination of the TDR measurement with transmission-line modeling (TLM); the second method simply relies on a couple of independent capacitance measurements (ICMs) performed through an LCR meter. As a further goal, the metrological performance of this last method is compared with that of the traditional method, thus validating its applicability. Experimental results and related uncertainty analysis on various samples demonstrate that the proposed alternative method is definitely suitable for a simpler and accurate estimation of the static electrical conductivity, also when dealing with moistened soils.