The structure of the title compound, [Zn(C60H60N4)].C7H8, represents a typical clathrate containing a host molecule of [5,10,15,20-tetrakis(4-tert-butylphenyl)porphyrinato]zinc(II) and a toluene guest molecule. The Zn atom occupies an inversion center and exhibits ideal square-planar coordination, while the porphyrin group remains perfectly flat. The toluene molecule lies on an inversion center and is disordered.
[5,10,15,20-Tetrakis(4-tert-butylphenyl)-porphyrinato-ĸ4N]zinc(II) toluene solvate
MELE, Giuseppe Agostino;DEL SOLE, Roberta
2007-01-01
Abstract
The structure of the title compound, [Zn(C60H60N4)].C7H8, represents a typical clathrate containing a host molecule of [5,10,15,20-tetrakis(4-tert-butylphenyl)porphyrinato]zinc(II) and a toluene guest molecule. The Zn atom occupies an inversion center and exhibits ideal square-planar coordination, while the porphyrin group remains perfectly flat. The toluene molecule lies on an inversion center and is disordered.File in questo prodotto:
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