Di-Me carbonate (DMC) is used as an alternative and eco-friendly solvent for selective cyclocarbonylation reactions of allyl phenol derivs. for the synthesis of lactones. In some cases, depending on the reaction condition, DMC behaves as a ring-opening reagent producing methoxycarbonyl compds., such as 2-OHC6H4(CH2)3CO2Me.

Palladium-catalysed cyclocarbonylation reactions in dimethyl carbonate, an eco-friendly solvent and ring-opening reagent.

VASAPOLLO, Giuseppe;MELE, Giuseppe Agostino;DEL SOLE, Roberta
2003-01-01

Abstract

Di-Me carbonate (DMC) is used as an alternative and eco-friendly solvent for selective cyclocarbonylation reactions of allyl phenol derivs. for the synthesis of lactones. In some cases, depending on the reaction condition, DMC behaves as a ring-opening reagent producing methoxycarbonyl compds., such as 2-OHC6H4(CH2)3CO2Me.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11587/300076
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