Di-Me carbonate (DMC) is used as an alternative and eco-friendly solvent for selective cyclocarbonylation reactions of allyl phenol derivs. for the synthesis of lactones. In some cases, depending on the reaction condition, DMC behaves as a ring-opening reagent producing methoxycarbonyl compds., such as 2-OHC6H4(CH2)3CO2Me.
Palladium-catalysed cyclocarbonylation reactions in dimethyl carbonate, an eco-friendly solvent and ring-opening reagent.
VASAPOLLO, Giuseppe;MELE, Giuseppe Agostino;DEL SOLE, Roberta
2003-01-01
Abstract
Di-Me carbonate (DMC) is used as an alternative and eco-friendly solvent for selective cyclocarbonylation reactions of allyl phenol derivs. for the synthesis of lactones. In some cases, depending on the reaction condition, DMC behaves as a ring-opening reagent producing methoxycarbonyl compds., such as 2-OHC6H4(CH2)3CO2Me.File in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.