Aziridines carrying three (or two) heteroaryl groups with electron-withdrawing effects were synthesised with sufficient diastereoselectivity. The cis aziridines are susceptible to ring opening and rearrangement when the formation of secondary enamines in stable hexacyclic structures with a N– H···N hydrogen bond is possible.

Synthesis and rearrangement of 1,2,3-Triheteroaryl(aryl)-substituted Aziridines

PINDINELLI, EMANUELA;TROISI, Luigino
2007-01-01

Abstract

Aziridines carrying three (or two) heteroaryl groups with electron-withdrawing effects were synthesised with sufficient diastereoselectivity. The cis aziridines are susceptible to ring opening and rearrangement when the formation of secondary enamines in stable hexacyclic structures with a N– H···N hydrogen bond is possible.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11587/108837
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