Double- and triple-decker phthalocyanine derivatives have been successfully used as the sensitive materials for liquid electrochemical sensors. The materials include homoleptic and heteroleptic phthalocyanine complexes formed by phthalocyanine, porphyrin and naphthalocyanine rings. A high degree of cross-selectiviy towards antioxidant compounds (including vannilic acid, pyrogallol, ascorbic acid and catechin) has been attained by using different phthalocyanine complexes. The features observed in the cyclic voltammograms reflect the rich electrochemistry of either the phthalocyanine molecules or the studied solutions. In consequence, each sensor shows a selective response to the antioxidant analysed. The obtained voltammograms from by using highly ordered electrodes prepared using the Langmuir–Blodgett (LB) or the Langmuir–Schaefer (LS) techniques show better resolution and stability than those of disordered electrodes prepared by casting. For this reason, ordered films have been chosen to construct an array of liquid sensors. The principal component analysis (PCA) of the obtained signals has allowed that a clear discrimination of the antioxidant solutions be achieved. The rich and varied responses produced by antioxidant molecules evidences that voltammetric

Langmuir-Blodgett and Langmuir-Schaefer films of homoleptic and heteroleptic phthalocyanine complexes as voltammetric sensors. Applications to the study of antioxidants

CASILLI, SERENA;VALLI, Ludovico;
2005-01-01

Abstract

Double- and triple-decker phthalocyanine derivatives have been successfully used as the sensitive materials for liquid electrochemical sensors. The materials include homoleptic and heteroleptic phthalocyanine complexes formed by phthalocyanine, porphyrin and naphthalocyanine rings. A high degree of cross-selectiviy towards antioxidant compounds (including vannilic acid, pyrogallol, ascorbic acid and catechin) has been attained by using different phthalocyanine complexes. The features observed in the cyclic voltammograms reflect the rich electrochemistry of either the phthalocyanine molecules or the studied solutions. In consequence, each sensor shows a selective response to the antioxidant analysed. The obtained voltammograms from by using highly ordered electrodes prepared using the Langmuir–Blodgett (LB) or the Langmuir–Schaefer (LS) techniques show better resolution and stability than those of disordered electrodes prepared by casting. For this reason, ordered films have been chosen to construct an array of liquid sensors. The principal component analysis (PCA) of the obtained signals has allowed that a clear discrimination of the antioxidant solutions be achieved. The rich and varied responses produced by antioxidant molecules evidences that voltammetric
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11587/103376
 Attenzione

Attenzione! I dati visualizzati non sono stati sottoposti a validazione da parte dell'ateneo

Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus ND
  • ???jsp.display-item.citation.isi??? ND
social impact