Catalytic amounts of aminium salts A-D induce the conversion of methylene chloride in solutions of several allyl and diallyl episulphides 1-6 into the corresponding unsaturated derivatives 7-12. The desulphurization process, which occurs through a plausible chain electron-transfer mechanism, rapid and may proceed in a fashion that preserves the stereochemistry of the starting episulphide.

Aminium Salts Induced Desulphurization of Allyl and Diallyl Thiiranes. Synthesis of Dienes and Trienes

MELE, Giuseppe Agostino
1995

Abstract

Catalytic amounts of aminium salts A-D induce the conversion of methylene chloride in solutions of several allyl and diallyl episulphides 1-6 into the corresponding unsaturated derivatives 7-12. The desulphurization process, which occurs through a plausible chain electron-transfer mechanism, rapid and may proceed in a fashion that preserves the stereochemistry of the starting episulphide.
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11587/102500
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