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EnglishVertically-aligned CdTe nanowire (NWs) were grown for the first time by metalorganic vapor phase epitaxy, using diisopropyl-telluride and dimethylcadmium as precursors, and Au nanoparticles as metal catalysts. The NWs were grown between 485 and 515, °C on (111)B-GaAs substrates, the latter overgrown with a 2-μm thick CdTe epilayer. To favor the Au-catalyst assisted process against planar deposition of CdTe, an alternate precursors flow process was adopted during NW self-assembly. Field emission electron microscopy observations and X-ray energy dispersive analyses of CdTe NWs revealed the presence of Au-rich droplets at their tips, the contact-angle between Au-droplets and NWs being, ~130°. The NW height increases exponentially with the growth temperature, indicating that the Au-catalyzed process is kinetics-limited (activation energy: ~57, kcal/mol), but no tapering is observed. Low temperature cathodoluminescence spectra recorded from single NWs evidenced a band-edge emission typical of zincblend CdTe, and a dominant (defects-related) emission band at 1.539 eV.
| Titolo: | Au-Catalyst Assisted MOVPE Growth of CdTe Nanowires for Photovoltaic Applications | |
| Autori: | LOVERGINE, Nicola (Corresponding) | |
| Data di pubblicazione: | 2018 | |
| Serie: | ||
| Abstract: | Vertically-aligned CdTe nanowire (NWs) were grown for the first time by metalorganic vapor phase epitaxy, using diisopropyl-telluride and dimethylcadmium as precursors, and Au nanoparticles as metal catalysts. The NWs were grown between 485 and 515, °C on (111)B-GaAs substrates, the latter overgrown with a 2-μm thick CdTe epilayer. To favor the Au-catalyst assisted process against planar deposition of CdTe, an alternate precursors flow process was adopted during NW self-assembly. Field emission electron microscopy observations and X-ray energy dispersive analyses of CdTe NWs revealed the presence of Au-rich droplets at their tips, the contact-angle between Au-droplets and NWs being, ~130°. The NW height increases exponentially with the growth temperature, indicating that the Au-catalyzed process is kinetics-limited (activation energy: ~57, kcal/mol), but no tapering is observed. Low temperature cathodoluminescence spectra recorded from single NWs evidenced a band-edge emission typical of zincblend CdTe, and a dominant (defects-related) emission band at 1.539 eV. | |
| Handle: | http://hdl.handle.net/11587/417945 | |
| ISBN: | 978-331966801-7 | |
| Appare nelle tipologie: | Relazione di atto di convegno in volume |
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