Novel nanostructured films employing hyperbranched and all-linear TiO2 nanorods have been developed with the aim to overcome the impediments to the diffusion of bulky redox shuttles in photo-electrochemical devices. The porosity of the working electrodes has been tailored by appropriately selecting the nanocrystal building blocks to study how the electrode features affect the electrochemical parameters underlying the charge-transport phenomena and the photovoltaic properties of dye-sensitized solar cells. An optimized combination of porosity, light-harvesting capability, and enhanced electron-transport properties leads to a remarkable improvement of the device efficiency from 1.3% to 8.6%. These results suggest that it is indeed possible to properly design photoanodes based on shape-engineered nanocrystals, which can be suitable for different electrochemical devices such as fuel cells or storage devices employing viscous or quasi-solid electrolytes.

Tailoring the Nanostructure of TiO2 Photoanodes for Efficient Co(II)/Co(III)-Mediated Dye-Sensitized Solar Cells

Rosabianca Iacobellis
Membro del Collaboration Group
;
Roberto Giannuzzi;Antonio Qualtieri
Membro del Collaboration Group
;
Pantaleo Davide Cozzoli
Conceptualization
;
Gian Paolo Suranna
Conceptualization
;
Luisa De Marco
Conceptualization
2017-01-01

Abstract

Novel nanostructured films employing hyperbranched and all-linear TiO2 nanorods have been developed with the aim to overcome the impediments to the diffusion of bulky redox shuttles in photo-electrochemical devices. The porosity of the working electrodes has been tailored by appropriately selecting the nanocrystal building blocks to study how the electrode features affect the electrochemical parameters underlying the charge-transport phenomena and the photovoltaic properties of dye-sensitized solar cells. An optimized combination of porosity, light-harvesting capability, and enhanced electron-transport properties leads to a remarkable improvement of the device efficiency from 1.3% to 8.6%. These results suggest that it is indeed possible to properly design photoanodes based on shape-engineered nanocrystals, which can be suitable for different electrochemical devices such as fuel cells or storage devices employing viscous or quasi-solid electrolytes.
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11587/418928
 Attenzione

Attenzione! I dati visualizzati non sono stati sottoposti a validazione da parte dell'ateneo

Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 2
  • ???jsp.display-item.citation.isi??? 3
social impact